How EPA’s four Best Available Technologies remove PFAS. Pick a technology, the compounds in the water and the operating conditions, then move through time to see which compounds break through first and what that does to run length and residuals.
As of October 18, 2026. The 2024 rule is in force as written: initial monitoring by April 26, 2027, MCL compliance by April 26, 2029. EPA’s May 2026 proposals to move the PFOA/PFOS date and to rescind the other limits are not final, and the D.C. Circuit challenge (No. 24-1188) was argued September 18, 2026 with no ruling as of this date.
| Compound | Gauge reference | Status |
|---|---|---|
| PFOA | 4 ng/L | MCL 4.0 ng/L in force. Compliance date April 26, 2029; EPA proposed moving it to 2031 (not final). |
| PFOS | 4 ng/L | MCL 4.0 ng/L in force. Compliance date April 26, 2029; EPA proposed moving it to 2031 (not final). |
| PFHxS | 10 ng/L | MCL 10 ng/L and Hazard Index in force. EPA proposed rescinding both in May 2026 (not final). |
| PFNA | 10 ng/L | MCL 10 ng/L and Hazard Index in force. EPA proposed rescinding both in May 2026 (not final). |
| HFPO-DA (GenX) | 10 ng/L | MCL 10 ng/L and Hazard Index in force. EPA proposed rescinding both in May 2026 (not final). |
| PFBS | 2,000 ng/L | No individual MCL. Counts only in the Hazard Index (health-based water concentration 2,000 ng/L), which EPA proposed rescinding. |
| PFBA | None | No federal MCL. Shown as a short-chain teaching example. |
Assumptions: one pool is 50 m × 25 m × 2 m = 2,500 m³ (2.5 million litres), so 20 pools hold 50 million litres; one drop is 0.05 mL. Four drops are 0.2 mL = 2 × 10⁻⁴ L, and 2 × 10⁻⁴ ÷ 5 × 10⁷ = 4 × 10⁻¹², four parts per trillion. The comparison is by volume; drinking-water limits are mass per volume (4 ng/L), which is equivalent for water.
GAC and resin use EPA’s pooled bed-life regressions, BV = A·(TOC or total PFAS) + AR·%R + B, evaluated at 50% removal. A log-logistic curve, C/C₀ = 1 / (1 + (BV50/BV)n), passes through that point. Its steepness n is set so the midpoint slope equals EPA’s linear slope (n = 4·BV50/|AR|), then bounded so that BV50/BV10 stays within the range observed by Chow et al. (GAC 1.2–2.7, resin 1.4–4.9). Days in service = BV × EBCT ÷ 1,440.
| Parameter | Value | Basis |
|---|---|---|
| GAC ATOC | -37,932 BV per mg/L | EPA T&C Table 2-6 (10-min EBCT; valid to TOC 3.2 mg/L) |
| GAC AR | -36,309 | EPA T&C Table 2-6 |
| GAC B, HFPO-DA | 113,034 BV | EPA T&C Table 2-6 |
| GAC B, PFBS | 129,357 BV | EPA T&C Table 2-6 |
| GAC B, PFHxS | 129,357 BV | EPA T&C Table 2-6 |
| GAC B, PFOA | 139,862 BV | EPA T&C Table 2-6 |
| GAC B, PFOS | 143,731 BV | EPA T&C Table 2-6 |
| GAC BV50, PFBA | 5,000 BV | Illustrative. No EPA equation. Bounded by full-scale complete breakthrough near 7,100 BV (Bertanza et al. 2020). No TOC effect applied. |
| AIX APFAS | -6.04 BV per ng/L | EPA T&C Table 3-5 (simulated 3.3-min EBCT; valid to 7,044 ng/L) |
| AIX AR | -198,242 | EPA T&C Table 3-5 |
| AIX B, PFOA | 390,787 BV | EPA T&C Table 3-5 |
| AIX B, PFBS | 439,515 BV | EPA T&C Table 3-5 |
| AIX B, PFHxS | 439,515 BV | EPA T&C Table 3-5 |
| AIX B, PFOS | 439,515 BV | EPA T&C Table 3-5 |
| Not modelled | — | PFNA on GAC and resin; HFPO-DA and PFBA on resin (EPA could not develop a breakthrough relationship). HFPO-DA on NF (no Treatability Database removal value). |
| TOC range | 0.5–2 mg/L | EPA’s cost-analysis bracket. Above about 2.4 mg/L the linear equation gives HFPO-DA a negative bed life, so the bench stops at 2.0. |
| EBCT, GAC | 7.5–26 min | Full-scale PFAS plants, EPA T&C §2.6.1. Bed volumes held constant across EBCT (simplification). |
| EBCT, resin | 2–6 min | Vendor range 3–6 min, EPA T&C §3.6.1 |
| GAC apparent density | 0.54 g/mL | Within 0.49–0.62 g/mL vendor datasheet range (Liu et al. 2019, Table 1). Resin density not sourced; no resin mass shown. |
| RO/NF removal | 95% | EPA’s planning assumption for concentrate estimates (T&C §4.2.2). Applied only where the Treatability Database reports a removal for that compound and membrane (maxima 98–99.9% for the compounds here). HFPO-DA on RO has only a lower bound (>64.2%, effluent below detection), so 95% is marked illustrative; HFPO-DA on NF has no value and is not modelled. |
| RO/NF recovery | 70–92% | EPA cost model 80% groundwater, 85% surface water, 70–75% small systems (T&C §7.4.1.4); full-scale plants 85–92% (§4.2.2) |
| Concentrate strength | (1 − r(1 − R)) ÷ (1 − r) | Mass balance. At 95% removal and 85–92% recovery this gives EPA’s “6 to 12 times” influent. |
| Change-out trigger | First compound to reach its reference | Single vessel, no lead-lag credit, as in EPA’s cost model (T&C §2.6.2) |
| Badge thresholds | 70% / 100% | Display convention used across PFAS Comply. Not regulatory. |
| Scenario influents | — | Illustrative teaching values, not real systems. “Load my system” uses the highest reported result per compound. |